Vinyl-Acrylic Copolymer for Contact Adhesive (Soft, flexible inyl-acrylic with high tack)
配方组成:
Methacrylic Acid/2.400 "Abex" VA-50/38.00 2-Ethylhexyl Acrylate/348.00 N-Methylol Acrylamide (60% sol'n.)/2.00 Na2S2O8/1.25 Vinyl Acetate/149.00 Water/410.00 Form A solution of "Abex" VA-50 and N-methylol acrylamide in 150 g of water. Blend monomers and form pre-emulsion by slowly adding the mixture to the surfactant solution while agitating vigorously. Add preemulsion to an addition funnel. To a 1 l resin kettle reactor add 220 g of water and Na2S2O8. Heat to 60'C while stirring and purging with nitrogen. Prepare a solution of NaHSO3 in 40 g of water and charge to an addition funnel. When the reaction temperature has reached 60'C charge 5.0 ml of the NaHSO3 solution and then begin addition of pre-emulsion. Schedule addition time for about 3 h. Maintain polymerization temperature at 65-70'C. The remaining NaHSO3 solution is added in 5.0 ml increments throughout the reaction as needed. After all ingredients have been add